%0 Journal Article %1 Wang.2003b %A Wang, Jianhui %A Li, Shoujian %A Zheng, Chong %A Maguire, John A. %A Kaim, Wolfgang %A Hosmane, Narayan S. %D 2003 %J Inorganic Chemistry Communications %K apart bisbenzene carbon complex crystal neodymacarborane potassium potassium;neodymacarborane prepn prepn;mol sandwich structure unsolvated %N 9 %P 1220--1223 %R 10.1016/S1387-7003(03)00227-2 %T Unsolvated \dqcarbons apart\dq neodymacarborane sandwich stabilized by bis(h6-benzene)potassium cation: A unique dimeric mixed-metal sandwiched ion-pair %V 6 %X The reaction between NdCl3 and K metal in a 1:4 molar ratio in THF, followed by the addn. of 2 equiv 1,2-(Me3Si)2-1,2-closo-C2B4H4 (1), produced the novel dimeric, mixed-metal sandwich ion pair, 2,2',4,4'-(SiMe3)4-5,6-(μ-H)2K(η6-C6H6)2-1,1'-commo-Nd(η5-2,4-C2B4H4)22 (2), in 78\% yield, after re-crystn. in benzene. The simultaneous cage opening/metalation product 2 was verified by single crystal x-ray diffraction. on SciFinder(R)

@article{Wang.2003b, abstract = {The reaction between NdCl3 and K metal in a 1:4 molar ratio in THF, followed by the addn. of 2 equiv 1,2-(Me3Si)2-1,2-closo-C2B4H4 (1), produced the novel dimeric, mixed-metal sandwich ion pair, {2,2',4,4'-(SiMe3)4-5,6-[(μ-H)2K(η6-C6H6)2]-1,1'-commo-Nd(η5-2,4-C2B4H4)2}2 (2), in 78{\%} yield, after re-crystn. in benzene. The simultaneous cage opening/metalation product 2 was verified by single crystal x-ray diffraction. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Wang, Jianhui and Li, Shoujian and Zheng, Chong and Maguire, John A. and Kaim, Wolfgang and Hosmane, Narayan S.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29a2a4b932bbccb934c72a5cb9301a206/huebleriac}, doi = {10.1016/S1387-7003(03)00227-2}, interhash = {0d2650991ee95336cb168d16e665c666}, intrahash = {9a2a4b932bbccb934c72a5cb9301a206}, issn = {1387-7003}, journal = {Inorganic Chemistry Communications}, keywords = {apart bisbenzene carbon complex crystal neodymacarborane potassium potassium;neodymacarborane prepn prepn;mol sandwich structure unsolvated}, number = 9, pages = {1220--1223}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Unsolvated {\dq}carbons apart{\dq} neodymacarborane sandwich stabilized by bis(\textgreek{h}6-benzene)potassium cation: A unique dimeric mixed-metal sandwiched ion-pair}, volume = 6, year = 2003 }