%0 Journal Article %1 Stange.1998 %A Stange, Andreas F. %A Sixt, Torsten %A Kaim, Wolfgang. %D 1998 %J Chemical Communications (Cambridge, United Kingdom) %K 1 complex complex;structure copper phenanthroline prepn structure structure;crystal thiolate %N 4 %P 469--470 %R 10.1039/a708867a %T Highly dissymmetric chelate coordination of 3,4,7,8-tetramethyl-1,10-phenanthroline to CuI(SR) %X Not only AuI and HgII species but also CuI(SR) fragments can bind in a highly dissym. fashion to sym. diimine chelate ligands. The 2 + 1 coordination arrangement obsd. for the metal in two complexes (tmphen)Cu(SR) (I; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline; R = 2,4,6-trimethylphenyl, 2,6-diphenylphenyl) is characterized by obtuse angles aN(1)-Cu-S \textgreater 159° and by two very different distances Cu-N(1) and Cu-N(2). I (R = 2,4,6-trimethylphenyl and 2,6-diphenylphenyl) are monoclinic, space group P21/n, R = 0.0501 and 0.0687, resp. on SciFinder(R)

@article{Stange.1998, abstract = {Not only AuI and HgII species but also CuI(SR) fragments can bind in a highly dissym. fashion to sym. diimine chelate ligands. The 2 + 1 coordination arrangement obsd. for the metal in two complexes (tmphen)Cu(SR) (I; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline; R = 2,4,6-trimethylphenyl, 2,6-diphenylphenyl) is characterized by obtuse angles \textgreek{a}[N(1)-Cu-S] {\textgreater} 159° and by two very different distances Cu-N(1) and Cu-N(2). I (R = 2,4,6-trimethylphenyl and 2,6-diphenylphenyl) are monoclinic, space group P21/n, R = 0.0501 and 0.0687, resp. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Stange, Andreas F. and Sixt, Torsten and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27af9d1438a993dfa6dd7bf0183b0df4a/huebleriac}, doi = {10.1039/a708867a}, interhash = {0711b058e748828228211464dca36d27}, intrahash = {7af9d1438a993dfa6dd7bf0183b0df4a}, issn = {1359-7345}, journal = {Chemical Communications (Cambridge, United Kingdom)}, keywords = {1 complex complex;structure copper phenanthroline prepn structure structure;crystal thiolate}, number = 4, pages = {469--470}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Highly dissymmetric chelate coordination of 3,4,7,8-tetramethyl-1,10-phenanthroline to CuI(SR)}, year = 1998 }